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Molecule with higher Lying Homo:- K IV ii o H N-H N n vs. 11 IH answer. : 2 - molecule with higher Lying Homo:- O H O vs. HG O o answer: 3)- molecule with greater strain energy in its minimum energy conformation: O I 2 answer:- 4. - more Likely to have an axial t -butyl group:- CH3 cit3 1) - vs. answer:- 5- more Likely to have a negative DS*:- o H M8 MOOR Meo heat to 11 IT H B 2 ,B-ome Na one + NaoMs ons 6). more Likely to have a position Ds*: ii U-H NaoH N a N + us 2 - (III 7 more molecule Likely to undergo am aintramolecular SW2 upon treatment with base. HS- Hs ST, I I H 8. - preferred product:- is H s Br NaoMe vs. 2111 Br 9 - more reactive toward addition of H-I vs. one Me 10) - product more likely to Form Via thermally allowed cy clitation of the Following altene. W N neat vs H H IV - product more Likely to Form Via thermally allowed cyclization. 1 Vs. 1 + answer:- (12). Faster reaction with NaI:- Br Br VS answer:- 13)- higher strain energy:- Bicyclo [2.2.13 hept-t-ene vs. bicyclo [2.2.1] hept - z-ene 14 more stable carbocation. e - CN Nor IS - more stable carbocation: > @ Us. 16 - more reactive toward Solvolysis inacet. acid. US. I I 17 Reaction with more negative P value:- Br H3CCOOH X + X # B. 18 Reaction with more postive f value o OCH3 ROH X H ROH Il X H o answer:- 19 - Proton more Likely to be replaced upon reaction with acetyl Chloride and A(cl3. 1s K vs. H K Nu2 OCH3 answer: 20 - Proton more Likely to be replaced upon reaction with acetyl chloride and AI C3 HE vs HK, N N answer: 21 - Reaction more Likely to have ahigh normal Primary KIE ( - 7-0) Br H2O US. Br ROH answer:- Reaction more Likely to have a high normal secondary KIE (2103) haN P D U.S OH HBr D stronger Bronsted base:- NH2 NH2 US. OCH3 OCH3 answer:- 24 stronger Bronsted acid:- NH2 NH2 Us. OCH3 OCH3 answer:- 25). more Likely to have a higher a value- vs. o answer:- 26 - Faster solvolyis in acetic acid. OSO2CH3 H3C02SO 1/ answer:- 27). Faster Solvolysis reaction in acetic acid. Br Br / / 2b - more I Likely to Form a stable carbocation. 11 Vs. 1-1 - F - which one Aromatic and Anti Aromatic = = = is - 11 N 1 H

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